Phen-NaDPO
货号:PR-ET-027
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著名的有机半导体材料,广泛应用于OPV、OLED中作为阴极界面材料(cathode interfacial material, CIM) 和空穴阻挡层。Phen-NaDPO具有高玻璃化转变温度(Tg=116 oC)与电子迁移率(10–4~10–3 cm2 V–1 S–1) 可以有效降低阴极的功函,从而提高有机光伏电池的光电转化效率和稳定性。
CAS NO.: | 1480371-38-7 |
Formula: | C34H23N2PO |
分子量: | 506.33 g/mol |
Grade: | > 99% (HPLC) |
产品颜色: | 白色固体/晶体 |
Tg;TGA: | 116 ºC;>350 ºC |
UV: | 320 nm (in CH2Cl2); 325 nm (solid state) |
PL: | 542 nm, 586 nm |
ue | 10-4~10-3 cm2V-1s-1
|
HOMO/LUMO: | HOMO 6.0 eV, LUMO 2.64 eV |
Package: | 1g / 5g / 10g |
别名: | 3-[6-(diphenylphosphinyl)-2-naphthalenyl]-1,10-Phenanthroline, (6-(1,10-phenanthrolin-3-yl)naphthalen-2-yl)diphenylphosphine oxide, 3-(6-diphenylphosphinyl(naphth-2-yl))-1,10-phenanthroline |
分类: | Cathode interfacial material (CIM),Electron transport layer (ETL) materials, Hole blocking layer (HBL) materials |
- Tan, W.‐Y., Wang, R., Li, M., Liu, G., Chen, P., Li, X.‐C., Lu, S.‐M., Zhu, H.L., Peng, Q.‐M., Zhu, X.‐H., Chen, W., Choy, W.C.H., Li, F., Peng, J. and Cao, Y. (2014), Lending Triarylphosphine Oxide to Phenanthroline: a Facile Approach to High‐Performance Organic Small‐Molecule Cathode Interfacial Material for Organic Photovoltaics utilizing Air‐Stable Cathodes. Adv. Funct. Mater., 24: 6540-6547. doi: 10.1002/adfm.201401685
- Seitkhan, A., Neophytou, M., Kirkus, M., Abou‐Hamad, E., Hedhili, M. N., Yengel, E., Firdaus, Y., Faber, H., Lin, Y., Tsetseris, L., McCulloch, I., Anthopoulos, T. D. (2019), Use of the Phen‐NaDPO:Sn(SCN)2 Blend as Electron Transport Layer Results to Consistent Efficiency Improvements in Organic and Hybrid Perovskite Solar Cells. Adv. Funct. Mater., 29: 1905810. doi: 10.1002/adfm.201905810
- Song, X., Gasparini, N., Nahid, M. M., Paleti, S. H. K., Li, C., Li, W., Ade, H., Baran, D. (2019), Efficient DPP Donor and Nonfullerene Acceptor Organic Solar Cells with High Photon‐to‐Current Ratio and Low Energetic Loss. Adv. Funct. Mater., 29: 1902441. doi: 10.1002/adfm.201902441
- Zhang H., Tan W.-Y., Fladischer S., Ke L.-L., Ameri T., Li N., Turbiez M., Spiecker E., Zhu X.-H., Cao Y., Brabec C. J. (2016) Roll to Roll Compatible Fabrication of Inverted Irganic Solar Cells with a Self-Organized Charge Selective Cathode Interfacial Layer. J. Mater. Chem. A, 4: 5032-5038. doi: 10.1039/C6TA00391E
- http://www.skllmd.com/zhuxuhui/130
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